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2 article(s) from Tlili, Anis

Copper-promoted/copper-catalyzed trifluoromethylselenolation reactions

Clément Ghiazza and
Anis Tlili

Beilstein J. Org. Chem. 2020, 16, 305–316, doi:10.3762/bjoc.16.30

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Graphical Abstract

Scheme 1: Process for the formation of C(sp³)–SeCF₃ bonds with [(bpy)CuSeCF₃]₂ developed by the group of Weng....

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Scheme 2: Trifluoromethylselenolation of vinyl and (hetero)aryl halides with [(bpy)CuSeCF₃]₂ by the group of ...

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Scheme 3: Trifluoromethylselenolation of terminal alkynes using [(bpy)CuSeCF₃]₂ by the group of You and Weng.

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Scheme 4: Trifluoromethylselenolation of carbonyl compounds with [(bpy)CuSeCF₃]₂ by the group of Weng.

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Scheme 5: Trifluoromethylselenolation of α,β-unsaturated ketones with [(bpy)CuSeCF₃]₂ by the group of Weng.

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Scheme 6: Trifluoromethylselenolation of acid chlorides with [(bpy)CuSeCF₃]₂ by the group of Weng.

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Scheme 7: Synthesis of 2-trifluoromethylselenylated benzofused heterocycles with [(bpy)CuSeCF₃]₂ by the group...

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Scheme 8: Difunctionalization of terminal alkenes and alkynes with [(bpy)CuSeCF₃]₂ by the group of Liang.

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Scheme 9: Synthesis of Me₄NSeCF₃.

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Scheme 10: Oxidative trifluoromethylselenolation of terminal alkynes and boronic acid derivatives with Me₄NSeCF...

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Scheme 11: Trifluoromethylselenolation of diazoacetates and diazonium salts with Me₄NSeCF₃ by the group of Goo...

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Scheme 12: Trifluoromethylselenolation with ClSeCF₃ by the group of Tlili and Billard.

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Scheme 13: Trifluoromethylselenolation with TsSeCF₃ by the group of Tlili and Billard.

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Scheme 14: Copper-catalyzed synthesis of a selenylated analog 30 of Pretomanid developed by the group of Tlili...

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Scheme 15: One-pot procedures for C–SeCF₃ bond formations developed by Hor and Weng, Deng and Xiao, and Ruepin...

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Review

Published 03 Mar 2020

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Electrophilic trifluoromethylselenolation of terminal alkynes with Se-(trifluoromethyl) 4-methylbenzenesulfonoselenoate

Clément Ghiazza,
Anis Tlili and
Thierry Billard

Beilstein J. Org. Chem. 2017, 13, 2626–2630, doi:10.3762/bjoc.13.260

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Scheme 1: Electrophilic addition of 1a to alkynes. Yields shown are those of isolated products; yields determ...

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Figure 1: Single-crystal X-ray structure of 3a.

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Scheme 2: Mechanism proposal.

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Scheme 3: Perfluoroalkylselenolation of alkynes. Yields shown are those of isolated products; yields determin...

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Full Research Paper

Published 07 Dec 2017

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